Chemistry (CHEM)

The terms indicated are expected but are not guaranteed. For the courses offered during any given term, consult the Schedule of Classes.

040x Preparation for Chemistry (4, FaSp) Elementary course to prepare students for chemistry 105abL. Strong emphasis on chemical mathematics and more significant laws, trends, and concepts of general chemistry. Not available for degree credit. Graded CR/NC. Lecture, 3 hours; discussion, 4 hours.

102xg Chemistry for the Non-Scientist (4, FaSpSm) Nonmathematical presentation of chemistry; introduction to basic chemistry, including organic, biological, and nuclear aspects. Not available for credit to chemistry majors. Lecture, 3 hours; discussion, 1 hour.

105aLg-bL General Chemistry (4-4, FaSpSm) Fundamental principles and laws of chemistry; laboratory work emphasizes quantitative procedures. Prerequisite to all more advanced courses in chemistry. Lecture, 3 hours; laboratory and discussion, 4 hours. Quiz, 1 hour. Prerequisite foaL: CHEM 040 or passing of placement test; for bL: CHEM 105aL or CHEM 115aL. (Duplicates credit in CHEM 115aL or CHEM 115bL.)

115aLg-bL Advanced General Chemistry (4-4, a: Fa; b: Sp) Equivalent to 105aLg-bL, but taught at a higher level for exceptionally well-prepared students. Admission to course by departmental approval only. Lecture, 3 hours; lab and discussion, 4 hours; quiz, 1 hour. Prerequisite for bL: CHEM 115aL. (Duplicates credit in CHEM 105aL or CHEM 105bL.)

290abcd Special Laboratory (1-1-1-1, FaSpSm) Laboratory component for CHEM 105a, 105b, 322a, or 322b for students with equivalent lecture credit from another institution. Prerequisite: consent of department head.

300L Analytical Chemistry (4, Fa) Theory and practice in chemical analysis, emphasizing instrumental techniques; error analysis, fractional distillation, extraction; chromatography; visible, ultraviolet, and infrared spectroscopy; introductions to electrochemistry and nuclear magnetic resonance spectroscopy. Lecture, 2 hours; laboratory and discussion. Prerequisite: CHEM 105bL or CHEM 115bL.

322abL Organic Chemistry (4-4, FaSpSm) Chemistry of the carbon compounds of the aliphatic and aromatic series; laboratory preparation of typical compounds of both series. Lecture, 3 hours jointly with 325abL; laboratory and discussion, 4 hours. For premedical and predental students and some categories of biology majors and engineers. Prerequisite for aL: CHEM 105bL or CHEM 115bL; for bL: CHEM 322aL.

325abL Organic Chemistry (4-4, a: Fa; b: Sp) Required of majors in chemistry. Lecture, 3 hours a week with 322abL; laboratory and discussion, 7 hours. Prerequisite for aL: CHEM 105bL or CHEM 115bL; for bL: CHEM 325aL.

332L Physical Chemical Measurements (4, Sp) Experimental study of topics discussed in 430ab; adsorption, magnetic susceptibility; electron spin resonance, kinetics, equilibria, molecular spectra and structure, viscosity, dielectric properties. Discussion, 1 hour; laboratory, 9 hours. Corequisite: CHEM 430b.

390 Special Problems (1-4) Supervised, individual studies. No more than one registration permitted. Enrollment by petition only.

423L Advanced Laboratory Techniques in Organic and Inorganic Chemistry (4, Sp) Advanced synthetic, analytical, and physical measurement techniques in organic and inorganic chemistry. Emphasis on laboratory work with discussion of theoretical background. Lecture, 2 hours; discussion, 1 hour; laboratory, 8 hours. Prerequisite: CHEM 300L, CHEM 322bL or CHEM 325bL.

426 Advanced Organic Chemistry (4, Fa) Advanced treatment of organic chemistry from a mechanistic point of view according to the following topics: polar and isopolar reactions, intermediates. Lecture, 3 hours; discussion, 1 hour. Prerequisite: CHEM 322bL or CHEM 325bL.

430ab Physical Chemistry (4-4, a: Fa; b: Sp) Kinetic theory; equations of state; thermodynamics; phase equilibria; chemical equilibrium; nuclear chemistry, wave mechanics; spectroscopy; statistical thermodynamics; kinetics; electrochemistry; surface and colloid chemistry. Lecture, 3 hours; discussion, 1 hour. Prerequisite for a: CHEM 300L, CHEM 322bL or CHEM 325bL; MATH 225 or MATH 226 or MATH 245; PHYS 152; for b: CHEM 430a and PHYS 153.

453 Advanced Inorganic Chemistry (4, Sp) Atomic structure, theory of bonding, molecular structure, metallic state, coordination compounds, transition and nontransition metals, magnetic and optical properties, crystal field theory, mechanism of reactions. Lecture, 3 hours; discussion, 1 hour. Prerequisite: CHEM 105bL or CHEM 115bL and CHEM 322bL or CHEM 325bL.

465L Chemical Instrumentation (4, Fa) Principles of operation of instruments used in physical sciences. Basic electronics, interconnection of building blocks, data acquisition and data reduction, noise, instrument systems. Lecture, 2 hours; laboratory, 6 hours. Prerequisite: CHEM 332L or CHEM 430b or departmental approval.

490x Directed Research (2-8, max 8, FaSpSm) Individual research and readings. Not available for graduate credit. Prerequisite: departmental approval.

515 Structure and Bonding in Inorganic and Organometallic Chemistry (4) An integrated core course of structure and bonding in inorganic, coordination and organometallic chemistry within an oxidation state framework. Symmetry, electronic properties.

516 Synthesis, Reactivity, and Mechanism in Inorganic and Organometallic Chemistry (4) A reactivity framework for inorganic and organometallic chemistry. Synthesis, reaction mechanisms and energetics. Homogeneous catalysis. Prerequisite: CHEM 515.

519 Biochemistry and Molecular Biology: An Introduction for Chemists (4) Amino acids and peptides; protein structure and function; enzyme kinetics; structure, analysis and synthesis of nucleic acids; chemical biology of DNA and RNA; biotechnology.

520 Bioinorganic Chemistry (2) Structure, function, and properties of metal ions and metal complexes in biological systems. Enzymatic catalysis, transport, oxygen carriers, and redox systems. Model systems. Prerequisite: CHEM 515.

526 Structure and Mechanism in Organic Chemistry (4) Review of modern structural theory of organic chemistry; and relation to the mechanisms of organic chemical reactions.

527 Synthetic Organic Chemistry (4) A survey of representative groups of widely used synthetic organic reactions; emphasis on scope, limitations, and stereochemical consequences.

533 Chemical Thermodynamics (2 or 4) Basic principles of thermodynamics; application to chemical problems; introduction to statistical methods; calculation of thermodynamic functions from spectroscopic data.

534 Chemical Kinetics (2 or 4) Analysis of reacting systems, chain reactions, theories of elementary gas reactions, unimolecular reactions, collisional energy transfer, kinetics of fast reactions in liquids, enzyme kinetics; selected topics. Lecture, 3 hours.

535 Introduction to Molecular Spectroscopy (4) Theory and experimental methods of molecular spectroscopy and applications to chemistry. Rotational, vibrational, electronic and nuclear magnetic resonance spectroscopies. Prerequisite: CHEM 544.

536 Molecular Dynamics (2 or 4) Potential energy surfaces, reaction dynamics, scattering theories, classical trajectories, statistical theories, molecular energy transfer, photodissociation dynamics, gas-surface interactions, experimental results, beam and laser techniques.

538 Mathematical Techniques of Physical Chemistry (4) Fundamentals and techniques of mathematics and physics. Linear algebra, differential equations, mechanics, electricity and magnetism. Applications to physical chemistry/chemical physics.

539 Surface Chemistry (4) Physical and chemical properties of solid surfaces; thermodynamics and kinetics of gas chemisorption; chemical bonding at surfaces; applications to catalysis and electronic materials.

540 Introduction to Statistical Mechanics (4) Study of macroscopic systems from molecular viewpoint using statistical mechanics: ensembles, fluctuations, gases, gas-solid interfaces, crystals, polymers, critical phenomena, non-equilibrium systems.

544 Introduction to Quantum Chemistry (4) Basic principles of quantum mechanics and their application to chemistry. Electronic structure of atoms and molecules.

550 Special Topics in Chemical Physics (2-4, max 8) Study of selected areas of chemical physics. Critical evaluation of recent advances in the field. Prerequisite: departmental approval.

561 Polymer Synthesis (4) Concepts of polymer structure and stereochemistry. Organic chemistry of polymerization reactions with emphasis on condensation, radical, cationic, anionic, and coordination-metathesis polymerization.

571 Polymer Physical Chemistry (4) Physical chemical description of macromolecules, bulk polymers, and polymer solutions. Chain structure, conformation and statistics; statistical thermodynamics; gels and networks; scattering; transport; relaxation; scaling laws.

588ab X-ray Crystallography (2-2) a: Single-crystal X-ray diffraction theory and experimental methods. b: Application of diffraction techniques to problems of current chemical and biological interest. Prerequisite: CHEM 588a before b.

590 Directed Research (1-12, FaSpSm) Research leading to the master's degree. Maximum units which may be applied to the degree to be determined by the department. Graded CR/NC.

594abz Master's Thesis (2-2-0, FaSpSm) Credit on acceptance of thesis. Graded IP/CR/NC.

599 Special Topics (2-4, max 8) Special topics in chemistry.

621 Organic Photochemistry (2) Survey of photochemical reactions and description of important photophysical processes operating in fluid media.

624 Organo Transition Metal Chemistry (2) Survey of principles of bonding, synthesis, and mechanisms of reaction of organometallic compounds. Discussion of applications to homogeneous catalysis and stoichiometric synthesis of organic molecules.

625 Chemical Applications of Magnetic Resonance Spectroscopy (4) Elementary theory of magnetic resonance spectroscopy, methods of spectral analysis, treatment of Fourier Transform methods and time dependent phenomena; recent applications in organic chemistry.

626 Natural Products Chemistry (2) Survey of the chemistry and biogenesis of the major classes of secondary metabolites along biogenetic lines: terpenes, aceto genins, and alkaloids.

661 Selected Topics in Polymer Synthesis (2-4, max 8) Advanced level study in selected areas of polymer synthesis. Critical evaluation of recent advances. Topic examples: ionic polymerization; stereo chemistry of polymers; silicon polymers; ladder polymers.

671 Selected Topics in Polymer Physical Chemistry (2-4, max 8) Advanced level study in selected areas of polymer physical chemistry. Critical evaluation of recent advances. Topic examples: polymer viscoelasticity; polymer dynamics; scaling concepts; electroactive polymers.

790 Research (1-12, FaSpSm) Research leading to the doctorate. Maximum units which may be applied to the degree to be determined by the department. Graded CR/NC.

794abcdz Doctoral Dissertation (2-2-2-2-0, FaSpSm) Credit on acceptance of dissertation. Graded IP/CR/NC.

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